Current Issue : October - December Volume : 2011 Issue Number : 1 Articles : 5 Articles
Heavy metals are among the most important sorts of contaminant in the environment. Several methods already used to clean up the environment from these kinds of contaminants, but most of them are costly and difficult to get optimum results. Currently, phytoremediation is an effective and affordable technological solution used to extract or remove inactive metals and metal pollutants from contaminated soil and water. This technology is environmental friendly and potentially cost effective. This paper aims to compile some information about heavy metals of arsenic, lead, and mercury (As, Pb, and Hg) sources, effects and their treatment. It also reviews deeply about phytoremediation technology, including the heavy metal uptake mechanisms and several research studies associated about the topics. Additionally, it describes several sources and the effects of As, Pb, and Hg on the environment, the advantages of this kind of technology for reducing them, and also heavy metal uptake mechanisms in phytoremediation technology as well as the factors affecting the uptake mechanisms. Some recommended plants which are commonly used in phytoremediation and their capability to reduce the contaminant are also reported....
Palladium(II) iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction. In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied. This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II) iodide within this oscillatory reaction. The species researched include methanol, palladium(II) iodide, potassium iodide, and carbon monoxide. Several chemical reactions were considered and applied in a modelling study. The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used....
Stearic acid solid lipid nanoparticles were prepared according to a new technique, called coacervation. The main goal of this experimental work was the entrapment of peptide drugs into SLN, which is a difficult task, since their chemical characteristics (molecular weight, hydrophilicity, and stability) hamper peptide-containing formulations. Insulin and leuprolide, chosen as model peptide drugs, were encapsulated within nanoparticles after hydrophobic ion pairing with anionic surfactants. Peptide integrity was maintained after encapsulation, and nanoparticles can act in vitro as a sustained release system for peptide....
A particle-laden flow inside solid gas cyclones has been studied using computational fluid dynamics (CFD). The effects of high temperatures and different particle loadings have been investigated. The Reynolds stress (RSM) model-predicted results, in the case of pure gas, are within engineering accuracy even at high temperatures. Using the granular mixture model for the cases of particle-laden flow, discrepancies occurred at relatively high loadings (up to 0.5?kg/m3). Since the pressure drop is strongly related to the friction inside the cyclone body, the concept of entropy generation has been employed to detect regions of high frictional effects. Friction has been observed to be important at the vortex finder wall, the bottom of the conical-part wall, and the interface separating the outer and the core streams. The discrepancies between the present numerical simulation and the experimental results taken from the existing literature, which are caused by the mixture and turbulence models simplifying assumptions, are discussed in this paper....
Particle size and morphology are important properties of pharmaceutical particles. Preparation of microparticles with uniform particle size and morphology is necessary in order to systematically relate these properties to the release behavior and other functionalities such as drug encapsulation and dissolution. In this study, we successfully prepared monodisperse, nonagglomerated chitosan microparticles in a single step by a novel spray-drying technique. The control of particle size and morphology of spray-dried microparticles was investigated experimentally. Microparticles with larger particle size can be produced when chitosan precursor of higher concentration was used. Storage time of chitosan precursor, drying temperature, and addition of lactose were shown to be crucial parameters that affect the particle morphology. Appropriate choice of the drying temperature and precursor storage time permitted control of the particle morphology, ranging from nearly spherical to cap-shaped. Surface characteristics of the particles can be finely tuned by the amount of lactose added into the chitosan precursor....
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